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Thermo Scientific Chemicals
1-Bromoadamantane, 99%
CAS: 768-90-1 | C10H15Br | 215.134 g/mol
化学物質識別子
CAS768-90-1
IUPAC Name1-bromoadamantane
Molecular FormulaC10H15Br
InChI KeyVQHPRVYDKRESCL-UHFFFAOYSA-N
SMILESBrC12CC3CC(CC(C3)C1)C2
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)White to cream to yellow to pale orange to orange
FormCrystals or powder or crystalline powder
Assay (GC)≥98.5%
Melting Point (clear melt)115.0-121.0°C
1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.
Solubility
It is soluble in organic solvents and insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. Keep away from Strong oxidizing agents.
1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.
Solubility
It is soluble in organic solvents and insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. Keep away from Strong oxidizing agents.
RUO – Research Use Only
General References:
- SL Regen .; JJ Besse .; J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.
- SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.
- Reduction with Tri-n-butyl tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).
- With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).
- Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).