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Thermo Scientific Chemicals
Methyl crotonate, 96%, trans-isomer
CAS: 623-43-8 | C5H8O2 | 100.12 g/mol
化学物質識別子
CAS623-43-8
IUPAC Namemethyl (2E)-but-2-enoate
Molecular FormulaC5H8O2
InChI KeyMCVVUJPXSBQTRZ-ONEGZZNKSA-N
SMILESCOC(=O)\C=C\C
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear colorless to pale yellow
Assay (GC)≥95.0%
Refractive Index1.4225-1.4285 @20?C
Identification (FTIR)Conforms
FormLiquid
Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.
Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.
RUO – Research Use Only
General References:
- Hajime Kabashima; Hideto Tsuji; Hideshi Hattori. Michael addition of methyl crotonate over solid base catalysts. Applied Catalysis A: General. 1997, 165 (1-2), 319-325.
- Robin D. Clark; Karl G. Untch. [2 + 2] Cycloadditions of silyl enol ethers and dimethyl acetylenedicarboxylate, dimethyl fumarate, and methyl crotonate. J. Org. Chem. 1979, 44 (2), 253-255.