Thermo Scientific Chemicals

1,7-Octadiyne, 98%, Thermo Scientific Chemicals

製品番号(カタログ番号): A15829.18
50 g, Each
Thermo Scientific Chemicals

1,7-Octadiyne, 98%, Thermo Scientific Chemicals

製品番号(カタログ番号): A15829.18
50 g, Each
数量
製品番号(カタログ番号): A15829.18
または、製品番号A15829-18

化学物質識別子

CAS
871-84-1
Identification (FTIR)
Conforms
Assay (GC)
≥97.5%
Appearance (Color)
Clear colorless to pale yellow
Form
Liquid
Refractive Index
1.4440-1.4480 @ 20?C

概要

1,7-Octadiyne is an useful bifunctional chain extension unit. It participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(?-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(?,η2-C8H7)(?-dppm)2.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,7-Octadiyne is an useful bifunctional chain extension unit. It participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(μ-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(μ,η2-C8H7)(μ-dppm)2.

Solubility
Not miscible or difficult to mix.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Incompatible with strong oxidizing agents.
RUO – Research Use Only

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