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Thermo Scientific Chemicals
Perfluoro-1-iodohexane, 98+%, stab. with copper
CAS: 355-43-1 | C6F13I | 445.95 g/mol
化学物質識別子
CAS355-43-1
IUPAC Name1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-6-iodohexane
Molecular FormulaC6F13I
InChI KeyBULLJMKUVKYZDJ-UHFFFAOYSA-N
SMILESFC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear colorless to purple
FormLiquid
Assay (GC)>98.0%
CommentStabilised with Copper powder
Refractive Index1.3270-1.3310 @ 20?C
It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.
Solubility
Not miscible or difficult to mix in water.
Notes
Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.
Solubility
Not miscible or difficult to mix in water.
Notes
Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only
General References:
- Qian Liu, et al. Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalyst fac-[Ir(ppy)]3.J. Polym. Sci.,2014,52(22), 3283-3291.
- Emily R. Berkeley,et al. Syntheses, Structural Characterizations, and Reactivity Studies of Half-Sandwich Cobalt, Rhodium, and Iridium Metallatricarbadecaboranyl Complexes.Organometallics.,2015,34(7), 1396-1407.