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Thermo Scientific Chemicals
1-Iodooctane, 98+%, stab. with copper
CAS: 629-27-6 | C8H17I | 240.128 g/mol
化学物質識別子
CAS629-27-6
IUPAC Name1-iodooctane
Molecular FormulaC8H17I
InChI KeyUWLHSHAHTBJTBA-UHFFFAOYSA-N
SMILESCCCCCCCCI
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear colorless to pale yellow
Assay (GC)≥98.0%
Identification (FTIR)Conforms
Refractive Index1.4865-1.4910 @ 20?C
StabilizerCopper wire
さらに表示
Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Alkylation of [2,2′-([2,2′-bipyridine]-6,6′-diyl)bis[phenolato]-N,N′,O,O′]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.
Solubility
Insoluble in water.
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light, bases.
Alkylation of [2,2′-([2,2′-bipyridine]-6,6′-diyl)bis[phenolato]-N,N′,O,O′]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.
Solubility
Insoluble in water.
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light, bases.
RUO – Research Use Only
General References:
- Raess PW, et al. J. Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen. Electroanal. Chem. 2007, 603 (1), 124-34.
- Danielle M Goken,; Dennis G Peters,; Jonathan A Karty,; James P Reilly. Alkylation of [2,2'-([2,2'-bipyridine]-6,6'-diyl)bis[phenolato]-N,N',O,O']nickel(II) during catalytic reduction of 1-iodooctane. Journal of Electroanalytical Chemistry. 2004, 564 123-132.