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Thermo Scientific Chemicals
1-Iodonaphthalene, 98%
CAS: 90-14-2 | C10H7I | 254.07 g/mol
化学物質識別子
CAS90-14-2
IUPAC Name1-iodonaphthalene
Molecular FormulaC10H7I
InChI KeyNHPPIJMARIVBGU-UHFFFAOYSA-N
SMILESIC1=C2C=CC=CC2=CC=C1
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear yellow to brown to dark brown or purple
FormLiquid
Assay (GC)≥97.5%
Refractive Index1.6990-1.7030 @ 20°C
1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.
Solubility
Slightly soluble in water.
Notes
Light sensitive. Incompatible with oxidizing agents.
1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.
Solubility
Slightly soluble in water.
Notes
Light sensitive. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- G.Kothandaraman; D.W.Pratt; D.S.Tinti. Optically detected magnetic resonance spectra of the lowest triplet state of 1-iodonaphthalene in durene at zero and high magnetic fields. J. Chem. Phys. 1975, 63,(3), 3337.
- Guillermo A.Lotz; Sara M.Palacios; Roberto A.Rossi. Stereoselective reaction of a chiral assisted amide enolate ion with 1-iodonaphthalene by the SRN1 mechanism. Tetrahedron Letters. 1994, 35,(42), 7711-7714.