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Thermo Scientific Chemicals
2-Methylbenzeneboronic acid, 98%
CAS: 16419-60-6 | C7H9BO2 | 135.96 g/mol
化学物質識別子
CAS16419-60-6
IUPAC Name(2-methylphenyl)boronic acid
Molecular FormulaC7H9BO2
InChI KeyNSJVYHOPHZMZPN-UHFFFAOYSA-N
SMILESCC1=CC=CC=C1B(O)O
さらに表示
仕様
スペックシート
スペックシートAssay (Aqueous acid-base Titration)≥97.5%
Assay (HPLC)≥97.5%
Proton NMRConforms to structure
Appearance (Color)White to cream
CommentMay contain varying amounts of anhydride
さらに表示
2-Methylbenzeneboronic acid is a reagent used for Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water, Ruthenium catalyzed direct arylation reactions, Ligand-free copper-catalyzed coupling reactions, Rhodium-catalyzed asymmetric 1,4-addition reactions. Reagent used in Preparation of chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction, Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Methylbenzeneboronic acid is a reagent used for Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water, Ruthenium catalyzed direct arylation reactions, Ligand-free copper-catalyzed coupling reactions, Rhodium-catalyzed asymmetric 1,4-addition reactions. Reagent used in Preparation of chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction, Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agent.
2-Methylbenzeneboronic acid is a reagent used for Pd-catalyzed arylation using Suzuki-Miyaura cross-coupling in water, Ruthenium catalyzed direct arylation reactions, Ligand-free copper-catalyzed coupling reactions, Rhodium-catalyzed asymmetric 1,4-addition reactions. Reagent used in Preparation of chiral monophosphorus ligands in asymmetric Suzuki-Miyaura coupling reaction, Human farnesyl pyrophosphate synthase inhibitors as antitumor agents for multiple myeloma cells
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agent.
RUO – Research Use Only
General References:
- Navid Dastbaravardeh; Michael Schnürch; Marko D Mihovilovic. Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates. Organic Letters. 2012, 14 (7), 1930-1933.
- Isidro Cobo; M Isabel Matheu; Sergio Castillón; Omar Boutureira; Benjamin G Davis. Phosphine-free Suzuki-Miyaura cross-coupling in aqueous media enables access to 2-C-aryl-glycosides. Organic Letters. 2012, 14 (7), 1728-1731.
- Conditions for ligand-free Suzuki cross-coupling of arylboronic acids with aryl iodides, catalyzed by Palladium(II) acetate, 10516, to give unsymmetrical biphenyls in high yield, are described: Org. Synth., 75, 61 (1997). See Appendix 5.