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Thermo Scientific™
2-Bromostyrene, 96%, stab. with ca 0.05% 4-tert-butylcatechol
CAS: 2039-88-5 | C8H7Br | 183.048 g/mol
化学物質識別子
CAS2039-88-5
IUPAC Name1-bromo-2-ethenylbenzene
Molecular FormulaC8H7Br
InChI KeySSZOCHFYWWVSAI-UHFFFAOYSA-N
SMILESBrC1=CC=CC=C1C=C
さらに表示
仕様
スペックシート
スペックシートSolution TestClear: 10% diethyl ether
Appearance (Color)Clear colorless to pale yellow
Assay (GC)≥95.0%
Solution TestClear: 10% methanol
FormLiquid
さらに表示
2-Bromostyrene is used as a cross linking agent in fire-resistant bromostyrene-crosslinked polyesters. Further, it is used to prepare trans-1-(2-bromophenyl)-2-(3-bromophenyl)ethene by reacting with 1-bromo-3-iodo-benzene, involving palladium(II) acetate as catalyst.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Bromostyrene is used as a cross linking agent in fire-resistant bromostyrene-crosslinked polyesters. Further, it is used to prepare trans-1-(2-bromophenyl)-2-(3-bromophenyl)ethene by reacting with 1-bromo-3-iodo-benzene, involving palladium(II) acetate as catalyst.
Solubility
Miscible with methanol.
Notes
Incompatible with acids, bases, oxidizing agents and halogens.
2-Bromostyrene is used as a cross linking agent in fire-resistant bromostyrene-crosslinked polyesters. Further, it is used to prepare trans-1-(2-bromophenyl)-2-(3-bromophenyl)ethene by reacting with 1-bromo-3-iodo-benzene, involving palladium(II) acetate as catalyst.
Solubility
Miscible with methanol.
Notes
Incompatible with acids, bases, oxidizing agents and halogens.
RUO – Research Use Only
General References:
- Muselli, M.; Baudeguin, C.; Hoarau, C.; Bischoff, L. Pd-Catalyzed direct C-H functionalization of imidazolones with aryl- and alkenyl halides. Chem. Commun. 2015, 51 (4), 745-748.
- Kitamura, T.; Muta, K.; Oyamada, J. Hypervalent Iodine-Mediated Fluorination of Styrene Derivatives: Stoichiometric and Catalytic Transformation to 2,2-Difluoroethylarenes. J. Org. Chem. 2015, 80 (21), 10431-10436.