(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine
Thermo Scientific Chemicals

(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine

CAS: 167316-27-0 | C21H23N2O2S | 367.49 g/mol
製品番号(カタログ番号) H27006.06
または、製品番号H27006-06
価格(JPY)
-
数量:
5 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS167316-27-0
IUPAC NameN-[(1S,2S)-2-azaniumyl-1,2-diphenylethyl]-4-methylbenzene-1-sulfonamide
Molecular FormulaC21H23N2O2S
InChI KeyUOPFIWYXBIHPIP-SFTDATJTSA-O
SMILESCC1=CC=C(C=C1)S(=O)(=O)N[C@H]([C@@H]([NH3+])C1=CC=CC=C1)C1=CC=CC=C1
さらに表示
Appearance (Color)White
Assay (Non-aqueous acid-base Titration)> 95.0%
Optical Rotation+29.2? ? 0.5? (c=1, chloroform)
Formcrystalline powder
Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Solubility
Solubility in hot Acetonitrile (almost transparency).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only
Takao Ikariya,; Shohei Hashiguchi,; Kunihiko Murata,; Ryoji Noyori. Preparation of Optically Active (R,R)-Hydrobenzoin from Benzoin or Benzil 1,2-Ethanediol, 1,2-diphenyl-, (1R,2R)-. Organic Syntheses. 2005,