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Thermo Scientific Chemicals
2-Acetylbenzeneboronic acid, 97%
CAS: 308103-40-4 | C8H9BO3 | 163.97 g/mol
化学物質識別子
CAS308103-40-4
IUPAC Name(2-acetylphenyl)boronic acid
Molecular FormulaC8H9BO3
InChI KeyZKAOVABYLXQUTI-UHFFFAOYSA-N
SMILESCC(=O)C1=CC=CC=C1B(O)O
さらに表示
仕様
スペックシート
スペックシートIdentification (FTIR)Conforms
Appearance (Color)White to yellow
FormPowder and/or chunks
Assay (HPLC)≥96.0%
2-Acetylphenylboronic acid is a reactant used for a variety of coupling reactions, as well as synthesis and hydroxy masking, Suzuki-Miyaura cross-coupling reactions, rhodium-catalyzed annulation of ynamides, transient masking of hydroxy groups, cationic palladium complex-catalyzed diastereoselective tandem annulation, hydrogen peroxide mediated formation of heteroaryl ethers and copper-catalyzed transmetalation and homocoupling.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Acetylphenylboronic acid is a reactant used for a variety of coupling reactions, as well as synthesis and hydroxy masking, Suzuki-Miyaura cross-coupling reactions, rhodium-catalyzed annulation of ynamides, transient masking of hydroxy groups, cationic palladium complex-catalyzed diastereoselective tandem annulation, hydrogen peroxide mediated formation of heteroaryl ethers and copper-catalyzed transmetalation and homocoupling.
Solubility
Slightly soluble in water.
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
2-Acetylphenylboronic acid is a reactant used for a variety of coupling reactions, as well as synthesis and hydroxy masking, Suzuki-Miyaura cross-coupling reactions, rhodium-catalyzed annulation of ynamides, transient masking of hydroxy groups, cationic palladium complex-catalyzed diastereoselective tandem annulation, hydrogen peroxide mediated formation of heteroaryl ethers and copper-catalyzed transmetalation and homocoupling.
Solubility
Slightly soluble in water.
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only
General References:
- Annamária Molnár, et. al. Suzuki-Miyaura cross-coupling reactions of halo derivatives of 4H-pyrido[1,2-a]pyrimidin-4-ones.Org Biomol Chem.,2011,9(19), 6559-6565.
- Benoit Gourdet, et al. Rhodium-catalyzed annulation of ynamides with bifunctional arylboron reagents.Org Lett.,2010,12(11), 2554-2557.