Benzophenone imine, 95%, Stab.
Benzophenone imine, 95%, Stab.
Benzophenone imine, 95%, Stab.
Thermo Scientific Chemicals

Benzophenone imine, 95%, Stab.

CAS: 1013-88-3 | C13H11N | 181.238 g/mol
製品番号(カタログ番号) H30110.06
または、製品番号H30110-06
価格(JPY)
-
数量:
5 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS1013-88-3
IUPAC Namediphenylmethanimine
Molecular FormulaC13H11N
InChI KeySXZIXHOMFPUIRK-UHFFFAOYSA-N
SMILESN=C(C1=CC=CC=C1)C1=CC=CC=C1
さらに表示
Appearance (Color)Clear colorless to yellow to yellow-brown
Refractive Index1.6150-1.6210 @ 20°C
FormLiquid
Assay (GC)≥94.0%
StabilizerApprox. 0.02% w/w Hydroquinone
Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Useful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Suzanne Fergus et. al. Nitrile ylide dimerization: investigation of the carbene reactivity of nitrile ylides.. Journal of Organic Chemistry. 2004, 69 (14),4663-4669.
  2. C. R. Noller. Diphenylmethane inime hydrochloride. Org. Synth. 10 (28).