Titanium(IV) chloride, 1M soln. in dichloromethane
Titanium(IV) chloride, 1M soln. in dichloromethane
Titanium(IV) chloride, 1M soln. in dichloromethane
Thermo Scientific Chemicals

Titanium(IV) chloride, 1M soln. in dichloromethane

CAS: 7550-45-0 | Cl4Ti | 189.667 g/mol
数量:
100 mL
500 mL
製品番号(カタログ番号) H31830.AP
または、製品番号H31830-AP
価格(JPY)
-
数量:
500 mL
一括またはカスタム形式をリクエストする
化学物質識別子
CAS7550-45-0
IUPAC Nametitanium(4+) tetrachloride
Molecular FormulaCl4Ti
InChI KeyXJDNKRIXUMDJCW-UHFFFAOYSA-J
SMILES[Cl-].[Cl-].[Cl-].[Cl-].[Ti+4]
さらに表示
Appearance (Color)Colorless to pale yellow to dark brown
FormLiquid
Assay (Titration ex Chloride)0.95-1.10M
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Solubility
Reacts with water.

Notes
Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers
RUO – Research Use Only

General References:

  1. Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.
  2. Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.