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6-Bromoimidazo[1,2-a]pyridine, 98%
6-Bromoimidazo[1,2-a]pyridine, 98%
6-Bromoimidazo[1,2-a]pyridine, 98%
Thermo Scientific Chemicals

6-Bromoimidazo[1,2-a]pyridine, 98%

CAS: 6188-23-4 | C7H5BrN2 | 197.035 g/mol
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数量:
1 g
5 g
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製品番号（カタログ番号） H34453.03
または、製品番号H34453-03
価格（JPY）
-
数量:
1 g
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化学物質識別子
CAS6188-23-4
IUPAC Name6-bromoimidazo[1,2-a]pyridine
Molecular FormulaC7H5BrN2
InChI KeyFXPMFQUOGYGTAM-UHFFFAOYSA-N
SMILESBrC1=CN2C=CN=C2C=C1
さらに表示
仕様Specification Sheetスペックシート
FormCrystals or powder or crystalline powder
Melting Point (clear melt)76.0-82.0?C
Appearance (Color)Pale yellow
Assay (GC)≥97.5%
It is used in organic syntheses and as pharmaceutical intermediates. The best results were obtained with lactams that could be introduced on the 6-bromoimidazo[1,2-a]pyridine. 1,2-dihydro-5-imidazo [1,2-a]pyridin-6-yl-6-methyl-2-oxo-3-pyridinecarbonitrile hydrochloride monohydrate 6 was synthesized in 5 steps from 6-bromoimidazo[1,2-a] pyridine using [2- 14 C] cyanoacetamide as the source of the radiolabel.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used in organic syntheses and as pharmaceutical intermediates. The best results were obtained with lactams that could be introduced on the 6-bromoimidazo[1,2-a]pyridine. 1,2-dihydro-5-imidazo [1,2-a]pyridin-6-yl-6-methyl-2-oxo-3-pyridinecarbonitrile hydrochloride monohydrate 6 was synthesized in 5 steps from 6-bromoimidazo[1,2-a] pyridine using [2- 14 C] cyanoacetamide as the source of the radiolabel.

Solubility
slightly soluble in water.

Notes
Incompatible with strong oxidizing agents. Store at room temperature.
RUO – Research Use Only

General References:

  1. Jamal Koubachi.; Saïd El Kazzouli.; Sabine Berteina-Raboin.; Abderrahim Mouaddib.; Gérald Guillaumet. Synthesis of Polysubstituted Imidazo[1,2-a]pyridines via Microwave-Assisted One-Pot Cyclization/Suzuki Coupling/Palladium-Catalyzed Heteroarylation.J. Org. Chem. 2007, 72 (20),7650-7655.
  2. Giuseppe Trapani.; Massimo Franco.; Laura Ricciardi .; Andrea Latrofa.; Giuseppe Genchi.; Enrico Sanna.; Francesca Tuveri.; Elisabetta Cagetti.; Giovanni Biggio.; Gaetano Liso. Synthesis and Binding Affinity of 2-Phenylimidazo[1,2-a]pyridine Derivatives for both Central and Peripheral Benzodiazepine Receptors. A New Series of High-Affinity and Selective Ligands for the Peripheral Type. J. Med. Chem. 1997, 40 (19),3109-3118.