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Thermo Scientific Chemicals
4-Nitrobenzeneboronic acid pinacol ester, 98%
CAS: 171364-83-3 | C12H16BNO4 | 249.073 g/mol
仕様
CAS171364-83-3
化学物質名または材質4-Nitrobenzeneboronic acid pinacol ester
式量249.08
IUPAC名4,4,5,5-tetramethyl-2-(4-nitrophenyl)-1,3,2-dioxaborolane
InChIキーLUWACRUAJXZANC-UHFFFAOYSA-N
さらに表示
4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.
Solubility
Slightly soluble in water.
Notes
Store in a cool, dry place, in a well sealed container. Store away from oxidizing agents.
4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.
Solubility
Slightly soluble in water.
Notes
Store in a cool, dry place, in a well sealed container. Store away from oxidizing agents.
RUO – Research Use Only
General References:
- Yu Li; Lian-Xun Gao; Fu-She Han. Reliable and diverse synthesis of aryl azides through copper-catalyzed coupling of boronic acids or esters with TMSN3.. Chemistry: A European Journal. 2010, 16 (27), 7969-7972.
- Aaron M Whittaker; Richard P Rucker; Gojko Lalic. Catalytic SN2'-selective substitution of allylic chlorides with arylboronic esters. Organic Letters. 2010, 12 (14), 3216-3218.