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Thermo Scientific Chemicals
Di(2-pyridyl) ketone, 98%
CAS: 19437-26-4 | C11H8N2O | 184.198 g/mol
化学物質識別子
CAS19437-26-4
IUPAC Name2-(pyridine-2-carbonyl)pyridine
Molecular FormulaC11H8N2O
InChI KeyQPOWUYJWCJRLEE-UHFFFAOYSA-N
SMILESO=C(C1=CC=CC=N1)C1=CC=CC=N1
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)White to cream to pale brown
Assay (chromatographic, GC or HPLC)≥97.5%
FormPowder or crystalline powder
di-2-Pyridyl ketone has been used in the preparation of unusual {Ni(II)(3)Ln(III)(?-OR)(6)}(3+) complexes with a star topology. Its monoanionic form has been used in the synthesis of triangular Ni(2)M (M = lanthanide, Y) complexes. The Schiff base ligands derived from di-2-pyridyl ketone exhibit ant proliferative activity in SK-N-MC neuroepithelioma (cancer) cells.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
di-2-Pyridyl ketone has been used in the preparation of unusual {Ni(II)(3)Ln(III)(μ-OR)(6)}(3+) complexes with a “star” topology. Its monoanionic form has been used in the synthesis of triangular Ni(2)M (M = lanthanide, Y) complexes. The Schiff base ligands derived from di-2-pyridyl ketone exhibit ant proliferative activity in SK-N-MC neuroepithelioma (cancer) cells.
Solubility
Low solubility in water.
Notes
Desiccate at room temperature. Keep away from oxidizing agents.
di-2-Pyridyl ketone has been used in the preparation of unusual {Ni(II)(3)Ln(III)(μ-OR)(6)}(3+) complexes with a “star” topology. Its monoanionic form has been used in the synthesis of triangular Ni(2)M (M = lanthanide, Y) complexes. The Schiff base ligands derived from di-2-pyridyl ketone exhibit ant proliferative activity in SK-N-MC neuroepithelioma (cancer) cells.
Solubility
Low solubility in water.
Notes
Desiccate at room temperature. Keep away from oxidizing agents.
RUO – Research Use Only
General References:
- Varughese Philipa.; V Suni.; Maliyeckal R Prathapachandra Kurup.; Munirathinam Nethaji. Structural and spectral studies of nickel(II) complexes of di-2-pyridyl ketone N4,N4-(butane-1,4-diyl) thiosemicarbazone. Polyhedron. 2004, 23 (7),1225-1233.
- Paul V. Bernhardt.; Lorraine M. Caldwell.; Timothy B.; Chaston, Piao Chin.; Des R. Richardson. Cytotoxic iron chelators: characterization of the structure, solution chemistry and redox activity of ligands and iron complexes of the di-2-pyridyl ketone isonicotinoyl hydrazone (HPKIH) analogues. J. Biol. Inorg. Chem. 2003, 8 (8),866-880.