1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

Name: 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%
SKU: H60395.06

CAS: 35193-63-6 | C20H13O4P | 348.294 g/mol

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数量:

1 g

5 g

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製品番号（カタログ番号） H60395.06

または、製品番号H60395-06

価格（JPY）

数量:

5 g

一括またはカスタム形式をリクエストする

化学物質識別子

CAS35193-63-6

IUPAC Name13-hydroxy-12,14-dioxa-13λ⁵-phosphapentacyclo[13.8.0.0²,¹¹.0³,⁸.0¹⁸,²³]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one

Molecular FormulaC20H13O4P

InChI KeyJEHUZVBIUCAMRZ-UHFFFAOYSA-N

SMILESOP1(=O)OC2=CC=C3C=CC=CC3=C2C2=C3C=CC=CC3=CC=C2O1

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仕様

スペックシート

Proton NMR>98.5%

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Solubility
Extremely low soluble in water.

Notes
Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

RUO – Research Use Only

General References:

H Nakamura.; A Sano.; H Sumii. Chiral Separation of (R, S)-1, 1'-Binaphthyl-2, 2'-diyl Hydrogenphosphate by Capillary Electrophoresis Using Monosaccharides as Chiral Selectors. Analytical sciences. 199814 (2), 375-378.