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Thermo Scientific Chemicals
Allyltrichlorosilane, 95%
CAS: 107-37-9 | C3H5Cl3Si | 175.508 g/mol
化学物質識別子
CAS107-37-9
IUPAC Nametrichloro(prop-2-en-1-yl)silane
Molecular FormulaC3H5Cl3Si
InChI KeyHKFSBKQQYCMCKO-UHFFFAOYSA-N
SMILESCl[Si](Cl)(Cl)CC=C
さらに表示
仕様
スペックシート
スペックシートIdentification (FTIR)Conforms
CommentMaterial Sourced in UK and US
Refractive Index1.4430-1.4490 @ 20?C (UK Sourced Material)
Appearance (Color)Clear colorless to pale yellow
Assay (GC)≥94.0%
さらに表示
Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.
Solubility
Soluble in THF, toluene, benzene. Reacts with water.
Notes
Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and moisture. Incompatible with water.
Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.
Solubility
Soluble in THF, toluene, benzene. Reacts with water.
Notes
Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and moisture. Incompatible with water.
RUO – Research Use Only
General References:
- Shū Kobayashi; Chikako Ogawa; Hideyuki Konishi and Masaharu Sugiura. Chiral Sulfoxides as Neutral Coordinate-Organocatalysts in Asymmetric Allylation of N-Acylhydrazones Using Allyltrichlorosilanes.J. Am. Chem. Soc.2003, 125 (22), 6610-6611.
- Ryoji Hirabayashi; Chikako Ogawa; Masaharu Sugiura and Shū Kobayashi. Highly Stereoselective Synthesis of Homoallylic Amines Based on Addition of Allyltrichlorosilanes to Benzoylhydrazones.J. Am. Chem. Soc.2001, 123 (39), 9493-9499.
- Allyltrichlorosilanes react with aldehydes in DMF without a catalyst to give high yields of the corresponding homoallylic alcohols, for example allyltrichlorosilane with benzaldehyde gives 1-phenyl-3-buten-1-ol and with cinnamaldehyde gives 1-phenyl-1,5-hexadien-3-ol, both in high yield: Tetrahedron Lett., 34, 3453 (1993); J. Org. Chem., 59, 6620 (1994).