Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.
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Applications
Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.
Solubility
Immiscible with water.
Notes
Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only
General References:
- Patel, N. C.; Schwarz, J. B.; Islam, K.; Miller, W.; Tran, T. P.; Wei, Y. Improved Synthesis of gamma-Lactones from Cyclopropyl Cyanoesters. Synth. Commun. 2011, 41 (15), 2209-2215.
- Huang, J. Y.; Zhuang, J. M.; Zou, Y. S. Substituent effects of accelerator on nitroxide-mediated radical polymerization. Macromol. Res. 2011, 19 (8), 757-763.