O-Benzylhydroxylamine, 96%
O-Benzylhydroxylamine, 96%
O-Benzylhydroxylamine, 96%
Thermo Scientific Chemicals

O-Benzylhydroxylamine, 96%

CAS: 622-33-3 | C7H9NO | 123.155 g/mol
製品番号(カタログ番号) L13601.14
または、製品番号L13601-14
価格(JPY)
-
数量:
25 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS622-33-3
IUPAC Namehydrogen O-benzylhydroxylamine chloride
Molecular FormulaC7H10ClNO
InChI KeyHYDZPXNVHXJHBG-UHFFFAOYSA-N
SMILES[H+].[Cl-].NOCC1=CC=CC=C1
さらに表示
Assay (GC)≥95.0%
FormLiquid
Identification (FTIR)Conforms
Refractive Index1.5375-1.5435 @ 20?C
Appearance (Color)Clear colorless to white to yellow
O-benzylhydroxylamine used in the synthesis of alfa- hydroxybenzylamines from alfa-hydroxyketones. It is also involved in the preparation of hydroxylamines and hydroxyamates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
O-benzylhydroxylamine used in the synthesis of alfa- hydroxybenzylamines from alfa-hydroxyketones. It is also involved in the preparation of hydroxylamines and hydroxyamates.

Solubility
Soluble in dimethylsulfoxide and methanol.

Notes
Store in a cool place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Jobbins, M. O.; Majewski, M. W.; Oliver, A. G.; Miller, M. J. Diastereoselective synthesis of a hydroxamate containing bicyclo-[3.2. 0] beta-lactam aminal via ruthenium alkene isomerization and Pd(II)-catalyzed oxidative amidation. Tetrahedron Lett. 2015, 56 (23), 3141-3143.
  2. Jeon, M.; Gupta, S.; Im, Y. W.; Rhee, Y. H.;Park, J. Fast and Complete Transimination of N-H Imines into O-Alkyl Oximes. Asian J. Org. Chem. 2015, 4 (4), 316-319.