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Thermo Scientific Chemicals
Chromium(II) chloride, anhydrous, 97%
CAS: 10049-05-5 | CrCl2
化学物質識別子
CAS10049-05-5
IUPAC Nameλ²-chromium(2+) dichloride
Molecular FormulaCl2Cr
InChI KeyXBWRJSSJWDOUSJ-UHFFFAOYSA-L
SMILES[Cl-].[Cl-].[Cr++]
さらに表示
スペックシートChromium(II) chloride is used as a precursor to other inorganic and organometallic chromium complexes. It is a reagent in the Nozaki-Hiyama-Kishi reaction. It is also used in the Takai olefination to prepare vinyl iodides from aldehydes in the presence of iodoform.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Chromium(II) chloride is used as a precursor to other inorganic and organometallic chromium complexes. It is a reagent in the Nozaki-Hiyama-Kishi reaction. It is also used in the Takai olefination to prepare vinyl iodides from aldehydes in the presence of iodoform.
Solubility
Soluble in water. Insoluble in alcohol and ether.
Notes
Hygroscopic. Incompatible with strong oxidizing agents, water and active metals.
Chromium(II) chloride is used as a precursor to other inorganic and organometallic chromium complexes. It is a reagent in the Nozaki-Hiyama-Kishi reaction. It is also used in the Takai olefination to prepare vinyl iodides from aldehydes in the presence of iodoform.
Solubility
Soluble in water. Insoluble in alcohol and ether.
Notes
Hygroscopic. Incompatible with strong oxidizing agents, water and active metals.
RUO – Research Use Only
General References:
- Sun, L.; Brennecke, J. F. Characterization of Imidazolium Chloride Ionic Liquids Plus Trivalent Chromium Chloride for ChromiumElectroplating. Ind. Eng. Chem. Res. 2015, 54 (17), 4879-4890.
- Ai, P.; Danopoulos, A. A.; Braunstein, P. N-Phosphanyl- and N,N'-Diphosphanyl-Substituted N-Heterocyclic Carbene Chromium Complexes: Synthesis, Structures, and Catalytic Ethylene Oligomerization. Organometallics 2015, 34 (16), 4109-4116.