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Thermo Scientific Chemicals
1,3,5-Triazine, 97%
CAS: 290-87-9 | C3H3N3 | 81.08 g/mol
化学物質識別子
CAS290-87-9
IUPAC Name1,3,5-triazine
Molecular FormulaC3H3N3
InChI KeyJIHQDMXYYFUGFV-UHFFFAOYSA-N
SMILESC1=NC=NC=N1
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)White to cream to yellow
Identification (FTIR)Conforms
Water Content (Karl Fischer Titration)≤1.5%
Melting Point (clear melt)72.0-83.0?C
Assay (GC)≥96.0%
さらに表示
1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.
Solubility
Soluble in ethanol (50 mg/ml), and methanol (100 mg/ml).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature. Store under dry inert gas.
1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.
Solubility
Soluble in ethanol (50 mg/ml), and methanol (100 mg/ml).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature. Store under dry inert gas.
RUO – Research Use Only
General References:
- N. G. McCormick.; J. H. Cornell.; A. M. Kaplan. Biodegradation of Hexahydro-1,3,5-Trinitro-1,3,5-Triazine. Appl. Environ. Microbiol.. 1981, 42 (5), 817-823.
- Francis H. Case.; Emil Koft. The Synthesis of Certain Substituted 1,3,5-Triazines Containing the Ferroin Group. J. Am. Chem. Soc. 1959, 81 (4), 905-906.
- Formylating agent: useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes: J. Am. Chem. Soc., 76, 290 (1954); Angew. Chem. Int. Ed., 6, 940 (1969); Arch. Pharm., 302, 828 (1969); 304, 362 (1971); with reactive substrates, formylation can be accomplished without a catalyst.
- Also reacts with nucleophiles, e.g. amines, which has been utilized in a quinazoline synthesis: J. Chem. Soc. (C), 1282 (1969):