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Thermo Scientific Chemicals
(S)-(+)-4-Methyl-2-pentanol, 99%
CAS: 14898-80-7 | C6H14O | 102.177 g/mol
化学物質識別子
CAS14898-80-7
IUPAC Name4-methylpentan-2-ol
Molecular FormulaC6H14O
InChI KeyWVYWICLMDOOCFB-UHFFFAOYNA-N
SMILESCC(C)CC(C)O
さらに表示
仕様
スペックシート
スペックシートRefractive Index1.4090-1.4120 @ 20?C
FormLiquid
Appearance (Color)Clear colorless
Optical Rotation20.5? ± 0.5? (neat)
Assay (GC)≥98.5%
It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.
Solubility
Slightly soluble in water. Soluble in alcohol.
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away. Protect from electrostatic charges.
It is employed in the reaction of 2-methoxyethyl acetals with allylsilanes in the presence of titanium tetrachloride: regioselective carbon-oxygen bond cleavage of the unsymmetrical acetals.
Solubility
Slightly soluble in water. Soluble in alcohol.
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away. Protect from electrostatic charges.
RUO – Research Use Only
General References:
- Mao-Ya Yin, et al. Asymmetric hydrogenation of ketones catalyzed by a silica-supported chitosan-palladium complex.J. Mol. Catal. A: Chem.,1999,147(1-2), 93-98.
- Philip E. Sonnet, et al. Kinetic resolutions of aliphatic alcohols with a fungal lipase from Mucor miehei.J. Org. Chem.,1987,52(15), 3477-3479.