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Thermo Scientific Chemicals
Tri-n-butyl(vinyl)tin, 96%
CAS: 7486-35-3 | C14H30Sn | 317.104 g/mol
化学物質識別子
CAS7486-35-3
IUPAC Nametributyl(ethenyl)stannane
Molecular FormulaC14H30Sn
InChI KeyQIWRFOJWQSSRJZ-UHFFFAOYSA-N
SMILESCCCC[Sn](CCCC)(CCCC)C=C
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear colorless to pale yellow
FormLiquid
Refractive Index1.4750-1.4810 @ 20?C
Assay (GC)≥95.0%
Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. It is also a vinyl nucleophile for bromoacetylene and bromoaromatics.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. It is also a vinyl nucleophile for bromoacetylene and bromoaromatics.
Solubility
Not miscible or difficult to mix in water.
Notes
Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. It is also a vinyl nucleophile for bromoacetylene and bromoaromatics.
Solubility
Not miscible or difficult to mix in water.
Notes
Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
RUO – Research Use Only
General References:
- Masahiro Yoshida, et al. Palladium-catalyzed ring expansion reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. stereospecific synthesis of (Z)-2-(3-aryl-1-propenyl)cyclopentanones.Orgc. Lett.,2004,6(12), 1979-1982.
- Ernesto G Occhiato, et al. Synthesis, biological activity, and three-dimensional quantitative structure-activity relationship model for a series of benzo[c]quinolizin-3-ones, nonsteroidal inhibitors of human steroid 5alpha-reductase 1.J. Med. Chem.,2004,47(14), 3546-3560.