Bismuth(III) nitrate pentahydrate, 98%

Name: Bismuth(III) nitrate pentahydrate, 98%
SKU: A11748.22
Price: 47.50 USD

CAS: 10035-06-0 | BiH10N3O14 | 485.07 g/mol

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Catalog number A11748.22

also known as A11748-22

Price (USD)

47.50

Each

Quantity:

100 g

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Price (USD)

47.50

Each

Chemical Identifiers

CAS10035-06-0

IUPAC Namebismuth(3+) pentahydrate trinitrate

Molecular FormulaBiH10N3O14

InChI KeyFBXVOTBTGXARNA-UHFFFAOYSA-N

SMILESO.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

Specifications

Specification Sheet

Identification (FTIR)Conforms

Water Content (Karl Fischer Titration)17.03-20.05% (4.5-5.5 waters)

Appearance (Color)White

Assay (unspecified)≥97.5%

FormCrystals or crystalline powder

Bismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Solubility
Soluble in dilute nitric acid solution, dilute acetic acid, glycerol and acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.

Notes
Hygroscopic. Moisture sensitive. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, powdered metals and organic materials.

RUO – Research Use Only

General References:

Useful, easily handled oxidizing and nitrating agent in organic synthesis. Montmorillonite KSF acidic clay impregnated with bismuth nitrate was found to be an excellent reagent for high-yield aromatic nitration: Tetrahedron Lett., 41, 8017 (2000). Phenols can be nitrated with the salt itself in acetone, or without solvent: J. Org. Chem., 70, 9071 (2005). In the presence of montmorillonite, alcohols can be oxidized to carbonyl compounds: Synth. Commun., 31, 2691 (2001). Reagent for deprotection of oximes: Synthesis, 1010 (2001), and hydrazones: Synth. Commun., 32, 1917 (2001). Thioamides and thioureas are readily converted to their oxo-analogs: Tetrahedron Lett., 44, 591 (2003).
Catalyst for a convenient, high-yield Michael addition of various substrates, including amines, imidazoles and indoles, to enones: J. Org. Chem., 68, 2109 (2003). Efficient catayst for tetrahydropyranylation and depyranylation of alcohols: Eur. J. Org. Chem., 4891 (2005).
For a brief feature on uses of the reagent in organic synthesis, see: Synlett, 2699 (2005).
Zahedifar, M.; Sheibani, H. Rapid three-component synthesis of pyrimidine and pyrimidinone derivatives in the presence of Bi(NO₃)₃·5H₂O as a mild and highly efficient catalyst. Res. Chem. Intermed. 2015, 41 (1), 105-111.
Pei, C. C.; Leung, W. W. F. Photocatalytic oxidation of nitrogen monoxide and o-xylene by TiO₂/ZnO/Bi₂O₃ nanofibers: Optimization, kinetic modeling and mechanisms. Appl. Catal., B 2015, 174, 515-525.