Search Thermo Fisher Scientific
Element Search
Structure SearchThermo Scientific Chemicals
Diethyl diallylmalonate, 97+%, Thermo Scientific Chemicals
Catalog number: A12460.09
10 g, Each
Thermo Scientific Chemicals
Diethyl diallylmalonate, 97+%, Thermo Scientific Chemicals
Catalog number: A12460.09
10 g, Each
Quantity
Catalog number: A12460.09
also known as A12460-09
Price (USD)
Price: 72.50
Online price: 61.65
Your price:
Quantity
-
Chemical Identifiers
CAS
3195-24-2
IUPAC Name
1,3-diethyl 2,2-bis(prop-2-en-1-yl)propanedioate
Molecular Formula
C13H20O4
InChI Key
LYUUVYQGUMRKOV-UHFFFAOYSA-N
SMILES
CCOC(=O)C(CC=C)(CC=C)C(=O)OCC
Specifications
Specification SheetAppearance (Color)
Clear colorless
Refractive Index
1.4440-1.4490 @ 20?C
Assay (GC)
≥97.0%
Form
Liquid
Description
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)
Notes
Store under cool dry place. Ensure good ventilation.
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)
Notes
Store under cool dry place. Ensure good ventilation.
RUO – Research Use Only
Figures
Documents & Downloads
Certificates
Search by lot number or partial lot number
Frequently asked questions (FAQs)
Citations & References
Search citations by name, author, journal title or abstract text