Thermo Scientific Chemicals

Ethyl 4-nitrobenzoylacetate, 97%, Thermo Scientific Chemicals

Catalog number: A17603.18
50 g, Each
Thermo Scientific Chemicals

Ethyl 4-nitrobenzoylacetate, 97%, Thermo Scientific Chemicals

Catalog number: A17603.18
50 g, Each
Quantity
Catalog number: A17603.18
also known as A17603-18
Price (USD)
Price: 286.00
Online price: 249.65
Your price:
Quantity
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Chemical Identifiers

CAS
838-57-3
IUPAC Name
ethyl 3-(4-nitrophenyl)-3-oxopropanoate
Molecular Formula
C11H11NO5
InChI Key
NGRXSVFCLHVGKU-UHFFFAOYSA-N
SMILES
CCOC(=O)CC(=O)C1=CC=C(C=C1)[N+]([O-])=O
Assay (HPLC)
≥96.0%
Form
Powder
Appearance (Color)
Yellow
Melting Point (clear melt)
63.0-73.0?C

Description

It is employed as a reactant involved in synthesis of β-1,3-dicarbonyl aldehydes via oxidation, knoevenagel condensation using a lysine catalyst, and cycloisomerization for the synthesis of trisubstituted furans. It is also a reactant for the fluorination by HF and iodosylbenzene, intramolecular Michael addition reactions and synthesis of diols. Also applied in the synthesis of diols via reduction of aromatic and aliphatic ketos esters6 and cross-coupling reactions for stereo selective synthesis of unsymmetrical 1,4-enediones.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is employed as a reactant involved in synthesis of β-1,3-dicarbonyl aldehydes via oxidation, knoevenagel condensation using a lysine catalyst, and cycloisomerization for the synthesis of trisubstituted furans. It is also a reactant for the fluorination by HF and iodosylbenzene, intramolecular Michael addition reactions and synthesis of diols. Also applied in the synthesis of diols via reduction of aromatic and aliphatic ketos esters6 and cross-coupling reactions for stereo selective synthesis of unsymmetrical 1,4-enediones.

Notes
Store away from oxidizing agents. Keep the container tightly closed in a cool, dry place.
RUO – Research Use Only

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