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Triethyl 2-phosphonopropionate, 98%, Thermo Scientific Chemicals
Catalog number: B23261.09
10 g, Each
Thermo Scientific Chemicals
Triethyl 2-phosphonopropionate, 98%, Thermo Scientific Chemicals
Catalog number: B23261.09
10 g, Each
Quantity
Catalog number: B23261.09
also known as B23261-09
Price (USD)
Price: 50.10
Online price: 42.65
Your price:
Quantity
-
Chemical Identifiers
CAS
3699-66-9
IUPAC Name
ethyl 2-(diethoxyphosphoryl)propanoate
Molecular Formula
C9H19O5P
InChI Key
BVSRWCMAJISCTD-UHFFFAOYNA-N
SMILES
CCOC(=O)C(C)P(=O)(OCC)OCC
Specifications
Specification SheetIdentification (FTIR)
Conforms
Refractive Index
1.4295-1.4335 @ 20?C
Appearance (Color)
Clear colorless
Form
Liquid
Assay (GC)
≥97.5%
Description
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
Solubility
Miscible with chloroform and methanol.
Notes
Incompatible with strong bases.
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
Solubility
Miscible with chloroform and methanol.
Notes
Incompatible with strong bases.
RUO – Research Use Only
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