Thermo Scientific Chemicals

4-Bromobenzeneboronic acid, 97+%, Thermo Scientific Chemicals

Catalog number: L01565.03
1 g, Each
Thermo Scientific Chemicals

4-Bromobenzeneboronic acid, 97+%, Thermo Scientific Chemicals

Catalog number: L01565.03
1 g, Each
Quantity
Catalog number: L01565.03
also known as L01565-03
Price (USD)
Price: 24.70
Online price: 20.65
Your price:
Quantity
-

Chemical Identifiers

CAS
5467-74-3
IUPAC Name
(4-bromophenyl)boronic acid
Molecular Formula
C6H6BBrO2
InChI Key
QBLFZIBJXUQVRF-UHFFFAOYSA-N
SMILES
OB(O)C1=CC=C(Br)C=C1
Form
Crystals or powder or crystalline powder or lumps or fused solid or flakes or granules
Assay (Aqueous acid-base Titration)
≥97.0%
Identification (FTIR)
Conforms
Proton NMR
Conforms to structure
Appearance (Color)
White to cream to pale brown

Description

4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.

Solubility
Soluble in methanol. Insoluble in water.

Notes
Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents. Incompatible with Oxidizing agents, Acids, Bases, Alcohols
RUO – Research Use Only

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