Thermo Scientific Chemicals

Magnesium bromide diethyl etherate, 98%, Thermo Scientific Chemicals

Catalog number: L15481.14
25 g, Each
Thermo Scientific Chemicals

Magnesium bromide diethyl etherate, 98%, Thermo Scientific Chemicals

Catalog number: L15481.14
25 g, Each
Quantity
Catalog number: L15481.14
also known as L15481-14
Price (USD)
Quantity
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Chemical Identifiers

CAS
29858-07-9
IUPAC Name
dibromomagnesium; ethoxyethane
Molecular Formula
C4H10Br2MgO
InChI Key
JGZKUKYUQJUUNE-UHFFFAOYSA-L
SMILES
Br[Mg]Br.CCOCC
Appearance (Color)
White to cream to brown or pale gray to gray
Form
Powder or crystalline powder and/or chunks/lumps
Assay (Titration ex Bromide)
≥97.5 to ≤102.5%

Description

The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The magnesium bromide diethyl etherate (MgBr2· OEt2)-methyl sulfide (Me2S) system is useful for the mild and chemo-selective deprotection of p-methoxybenzyl (PMB) ether. Lewis acid for catalysis of Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene. Magnesium bromide diethyl etherate is used in the synthesis of silicon-containing azole derivatives.

Solubility
Hydrolyzes in water.

Notes
Moisture sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.
RUO – Research Use Only

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