2-Bromoethanol, 97%
2-Bromoethanol, 97%
2-Bromoethanol, 97%
Thermo Scientific Chemicals

2-Bromoethanol, 97%

CAS: 540-51-2 | C2H5BrO | 124.965 g/mol
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Catalog number A10275.14
also known as A10275-14
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25 g
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Chemical Identifiers
CAS540-51-2
IUPAC Name2-bromoethan-1-ol
Molecular FormulaC2H5BrO
InChI KeyLDLCZOVUSADOIV-UHFFFAOYSA-N
SMILESOCCBr
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear colorless to pale yellow
Refractive Index1.4900-1.4965 @ 20?C
FormLiquid
Identification (FTIR)Conforms
Assay (GC)≥96.0%
2-Bromoethanol is utilized in selective reduction of nitroarenes. It is used as a solvent and organic synthetic raw material. It finds application in the synthesis of 2-piperidin-1-yl-ethanol by reacting with piperidine. It is used in selective reduction of nitroarenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Bromoethanol is utilized in selective reduction of nitroarenes. It is used as a solvent and organic synthetic raw material. It finds application in the synthesis of 2-piperidin-1-yl-ethanol by reacting with piperidine. It is used in selective reduction of nitroarenes.

Solubility
Miscible with water, organic solvent and petroleum ether.

Notes
Light sensitive. Hygroscopic. Store in a cool place. Incompatible with strong acids, strong oxidizing agents, strong reducing agents, acid chlorides and acid anhydrides.
RUO – Research Use Only

General References:

  1. Carboxylic acids protected as their 2-bromoethyl esters are readily deprotected by cleavage with sodium trithiocarbonate: Synthesis, 715 (1974). 2-Bromoethyl esters of amino acids have been cleaved by conversion with NaI (Finkelstein) to the corresponding iodo esters, followed by reductive cleavage with Zn in DMF: Chem. Ber., 112, 2145 (1979); Angew. Chem. Int. Ed., 20, 894 (1981). See also Appendix 6.
  2. Bao, J.; Tranmer, G. K. The utilization of copper flow reactors in organic synthesis. Chem. Commun. 2015, 51 (15), 3037-3044.
  3. Davis, O. A.; Croft, R. A.; Bull, J. A. Synthesis of diversely functionalised 2, 2-disubstituted oxetanes: fragment motifs in new chemical space. Chem. Commun. 2015, 51 (84), 15446-15449.