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Thermo Scientific Chemicals
Bis(pentafluorophenyl)phenylphosphine, 97%
CAS: 5074-71-5 | C18H5F10P | 442.20 g/mol
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Catalog number A11014.01
also known as A11014-01
Price (USD)
95.70
Each
Quantity:
0.25 g
Price (USD)
95.70
Each
Chemical Identifiers
CAS5074-71-5
IUPAC Namebis(2,3,4,5,6-pentafluorophenyl)(phenyl)phosphane
Molecular FormulaC18H5F10P
InChI KeyOYNXPGGNQMSMTR-UHFFFAOYSA-N
SMILESFC1=C(F)C(F)=C(P(C2=CC=CC=C2)C2=C(F)C(F)=C(F)C(F)=C2F)C(F)=C1F
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Specifications
Specification Sheet
Specification SheetAppearance (Color)White
FormPowder
Assay (GC)≥96.0%
Melting Point (clear melt)55.0-64.0?C
Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.
Solubility
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.
Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.
Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.
Solubility
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.
Notes
Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.
RUO – Research Use Only
General References:
- Gallotta, F. D. C.; Christensen, J. H. Source identification of petroleum hydrocarbons in soil and sediments from Iguaçu River Watershed, Paraná, Brazil using the CHEMSIC method (CHEMometric analysis of Selected Ion Chromatograms). J. Chromatogr. A 2012, 1235, 149-158.
- Kristensen, M.; Johnsen, A. R.; Christensen, J. H. Marine biodegradation of crude oil in temperate and Arctic water samples. J. Hazard. Mater. 2015, 300, 75-83.