Allyl iodide, 97+%, stab. with copper, Thermo Scientific Chemicals
Allyl iodide, 97+%, stab. with copper, Thermo Scientific Chemicals
Allyl iodide, 97+%, stab. with copper, Thermo Scientific Chemicals
Thermo Scientific Chemicals

Allyl iodide, 97+%, stab. with copper, Thermo Scientific Chemicals

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Catalog NumberQuantity
A11822.18
also known as A11822-18
50 g
Catalog number A11822.18
also known as A11822-18
Price (USD)
112.00
Each
Quantity:
50 g
Request bulk or custom format
Price (USD)
112.00
Each
Chemical Identifiers
CAS556-56-9
SpecificationsSpecification SheetSpecification Sheet
Refractive Index1.5515-1.5565 @ 20°C (non-U.S. sourced material)
FormLiquid
CommentMaterial sourced in the U.S. and in other countries
StabilizerCopper powder
Assay (GC)≥96.0%
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Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Solubility
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.

Notes
Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with heat, light, amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
RUO – Research Use Only

General References:

  1. B. Grzybowska; J. Haber; J. Janas. Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons. Journal of Catalysis.1977, 49 150-163.
  2. Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama. Tetrahedron Letters.1981, 49 4987-4988.
  3. Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).