Bromocyclopropane, 99%
Bromocyclopropane, 99%
Bromocyclopropane, 99%
Thermo Scientific Chemicals

Bromocyclopropane, 99%

CAS: 4333-56-6 | C3H5Br | 120.977 g/mol
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Catalog number A14996.18
also known as A14996-18
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251.65
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50 g
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Price (USD)
251.65
Online Exclusive
279.00
Save 27.35 (10%)
Each
Chemical Identifiers
CAS4333-56-6
IUPAC Namebromocyclopropane
Molecular FormulaC3H5Br
InChI KeyLKXYJYDRLBPHRS-UHFFFAOYSA-N
SMILESBrC1CC1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear, colourless to pale yellow
Assay (GC)>98.5%
Refractive Index1.4585-1.4615
Formliquid
Bromo Cyclopropane is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products. It is also used in the production of cyclopropyl boric acid. It is used as an intermediate in organic synethesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bromo Cyclopropane is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products. It is also used in the production of cyclopropyl boric acid. It is used as an intermediate in organic synethesis.

Solubility
It is soluble in chloroform, and methanol. Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8°C. Keep away from strong oxidizing agents, strong bases.
RUO – Research Use Only

General References:

  1. John F. Garst.; Ferenc Ungvary.; Rajnish Batlaw.; Kathryn Easton Lawrence. Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. J. Am. Chem. Soc. 1991, 113, (14), 5392-5397.
  2. CJ Wurrey.; RJ Berry.; YY Yeh.; TS Little. Vibrational spectra of bromocyclopropane Journal of Raman Spectroscopy. 1983, 14, (2), 87-92.
  3. The Grignard reagent functions as an allyl anion equivalent in the reaction with thioacetals catalyzed by Dichlorobis(triphenyl phosphine) nickel(II) , 13930: J. Am. Chem. Soc., 111, 9119 (1989):
  4. The lithio-derivative reacts with Bis(cyclopentadienyl) titanium dichloride, A11456, to give bis(cyclopropyl)titanocene, which reacts with carbonyl compounds to give alkylidenecyclopropane derivatives: Tetrahedron Lett., 34, 943 (1993). Similarly, esters and lactones give enol ethers and acetylenes give vinylcyclopropanes.