Methyl 4-bromobenzoate, 98+%
Methyl 4-bromobenzoate, 98+%
Methyl 4-bromobenzoate, 98+%
Methyl 4-bromobenzoate, 98+%
Thermo Scientific Chemicals

Methyl 4-bromobenzoate, 98+%

CAS: 619-42-1 | C8H7BrO2 | 215.046 g/mol
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Catalog number A15517.06
also known as A15517-06
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Quantity:
5 g
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Price (USD)
55.65
Online Exclusive
61.30
Save 5.65 (9%)
Each
Add to cart
Chemical Identifiers
CAS619-42-1
IUPAC Namemethyl 4-bromobenzoate
Molecular FormulaC8H7BrO2
InChI KeyCZNGTXVOZOWWKM-UHFFFAOYSA-N
SMILESCOC(=O)C1=CC=C(Br)C=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to cream to pale gray
Assay (GC)≥98.0%
FormCrystals or powder or crystalline powder
Melting Point (clear melt)76.0-83.0?C
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Suitable for battery materials development.

Applications
Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.

Solubility
Insoluble in water.

Notes
Incompatible with strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Frieman, B. A. An environmentally-friendly one-pot synthesis of 4-sulfonyl benzoic acids. Tetrahedron Lett. 2014, 55 (22), 3295-3298.
  2. Cui, X.; Wang, S.; Zhang, Y.; Deng, W.; Qian, Q.; Gong, H. Nickel-catalyzed reductive allylation of aryl bromides with allylic acetates. Org. Biomol. Chem. 2013, 11 (19), 3094-3097.