Hexamethylditin, 97%

Name: Hexamethylditin, 97%
SKU: A17638.03

CAS: 661-69-8 | C6H18Sn2 | 327.63 g/mol

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Catalog number A17638.03

also known as A17638-03

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1 g

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Chemical Identifiers

CAS661-69-8

IUPAC Namehexamethyldistannane

Molecular FormulaC6H18Sn2

InChI KeyCCRMAATUKBYMPA-UHFFFAOYSA-N

SMILESC[Sn](C)(C)[Sn](C)(C)C

Specifications

Specification Sheet

Assay (GC)≥96.0%

Refractive Index1.5385-1.5435 @ 20°C

Identification (FTIR)Conforms

Appearance (Color)Colorless to pale yellow

FormClear to hazy or turbid liquid

It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.

Solubility
Not miscible or difficult to mix in water.

Notes
Air Sensitive. Keep away from oxidizing agents, heat and air. Store under inert gas.

RUO – Research Use Only

General References:

Olov A. Wallner and Kálmán J. Szabó. Regioselective Palladium-Catalyzed Electrophilic Allylic Substitution in the Presence of Hexamethylditin.Org. Lett.,2004,4(9), 1563-1566.
E.W. Abel.; S. Moorhouse. Utilization of hexamethylditin in the synthesis of organotin-transitional metal complexes.J. Organomet. Chem.1970,24(3), 687-690.