5-Methylimidazole-4-carboxaldehyde, 99%, Thermo Scientific Chemicals
5-Methylimidazole-4-carboxaldehyde, 99%, Thermo Scientific Chemicals
5-Methylimidazole-4-carboxaldehyde, 99%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

5-Methylimidazole-4-carboxaldehyde, 99%, Thermo Scientific Chemicals

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Catalog NumberQuantity
B20608.06
also known as B20608-06
5 g
Catalog number B20608.06
also known as B20608-06
Price (USD)
97.00
Each
Quantity:
5 g
Request bulk or custom format
Price (USD)
97.00
Each
Chemical Identifiers
CAS68282-53-1
IUPAC Name5-methyl-1H-imidazole-4-carbaldehyde
Molecular FormulaC5H6N2O
InChI KeyKMWCSNCNHSEXIF-UHFFFAOYSA-N
SMILESCC1=C(C=O)N=CN1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)White to cream or yellow
FormPowder
Assay (GC)≥97.5%
Free acid (titration)≤1.5%
4-Methyl-5-imidazolecarboxaldehyde is suitable for use in the synthesis of 1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]-propan-2-ol (BIPO), 1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propane (BIP), {acetatoaqua[[(4-methylimidazol-5-yl)methylene]histamine]-copper(II)} perchlorate, Schiff base condensates with tris(2-aminoethyl)amine (tren) or tris(3-aminopropyl)amine (trpn). It is also used in the synthesis of imidazolate-based metal organic framework (MOF) membrane, 3,11-bis(4-imidazolylmethyl)-7-methyl-3,7,11,17-tetraazabicyclo[11.3.1]hepta-deca-1(17),13,15-triene, a 4-imidazolyl derivative of a 14-membered tetraazamacrocycle and Cu(II) eight and six coordinate compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Methyl-5-imidazolecarboxaldehyde is suitable for use in the synthesis of 1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]-propan-2-ol (BIPO), 1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propane (BIP), {acetatoaqua[[(4-methylimidazol-5-yl)methylene]histamine]-copper(II)} perchlorate, Schiff base condensates with tris(2-aminoethyl)amine (tren) or tris(3-aminopropyl)amine (trpn). It is also used in the synthesis of imidazolate-based metal organic framework (MOF) membrane, 3,11-bis(4-imidazolylmethyl)-7-methyl-3,7,11,17-tetraazabicyclo[11.3.1]hepta-deca-1(17),13,15-triene, a 4-imidazolyl derivative of a 14-membered tetraazamacrocycle and Cu(II) eight and six coordinate compounds.

Solubility
Soluble in water, (23 g/L) (25°C).

Notes
Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only

General References:

  1. Long LS, et al. Syntheses, crystal structures and properties of copper (II) complexes of 1, 3-bis [(4-methyl-5-imidazol-1-yl) ethylideneamino] propan-2-ol and 1, 3-bis [(4-methyl-5-imidazol-1-yl) ethylideneamino] propane.Transit. Met. Chem.1999,24(4), 440-444.
  2. Long LS, et al. Synthesis, crystal structure and cyclic voltammetry of square-pyramidal acetatoaqua [(4-methylimidazol-5-yl) methylene] histamine copper (II) perchlorate.Transit. Met. Chem.1999,24(1), 49-51.