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Dithiooxamide, 98%
CAS: 79-40-3 | C2H4N2S2 | 120.188 g/mol
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Catalog number B24866.14
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337.65
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Quantity:
25 g
Price (USD)
337.65
Online Exclusive
375.00Save 37.35 (10%)
Each
Chemical Identifiers
CAS79-40-3
IUPAC Nameethanedithioamide
Molecular FormulaC2H4N2S2
InChI KeyOAEGRYMCJYIXQT-UHFFFAOYSA-N
SMILESNC(=S)C(N)=S
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Specifications
Specification Sheet
Specification SheetFormCrystals or powder or crystalline powder
Identification (FTIR)Conforms
Elemental AnalysisC: 19.49-20.48% (Theory: 19.98(5)%)
Appearance (Color)Orange to dark orange to red
Elemental AnalysisN: 22.72-23.89% (Theory: 23.31%)
Dithiooxamide acts as a chelating agent and used in the determination of copper(II), nickel(II) and cobalt(II). It is used as a building block in the synthesis of cyclen. It is involved in the preparation of thiazolothiazole-linked porous organic polymers and N,N'-disubstituted dithiooxamides. It is also employed as a modifier to prepare the modified glassy carbon electrode which is used to investigate the electrochemical properties of quercetin, an important flavonoid derivative. Further, it is involved in the preparation of chelating resin with formaldehyde, which finds application in separation and concentration of silver ions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Dithiooxamide acts as a chelating agent and used in the determination of copper(II), nickel(II) and cobalt(II). It is used as a building block in the synthesis of cyclen. It is involved in the preparation of thiazolothiazole-linked porous organic polymers and N,N′-disubstituted dithiooxamides. It is also employed as a modifier to prepare the modified glassy carbon electrode which is used to investigate the electrochemical properties of quercetin, an important flavonoid derivative. Further, it is involved in the preparation of chelating resin with formaldehyde, which finds application in separation and concentration of silver ions.
Solubility
Soluble in acetone and chloroform. Insoluble in water.
Notes
Incompatible with oxidizing agents.
Dithiooxamide acts as a chelating agent and used in the determination of copper(II), nickel(II) and cobalt(II). It is used as a building block in the synthesis of cyclen. It is involved in the preparation of thiazolothiazole-linked porous organic polymers and N,N′-disubstituted dithiooxamides. It is also employed as a modifier to prepare the modified glassy carbon electrode which is used to investigate the electrochemical properties of quercetin, an important flavonoid derivative. Further, it is involved in the preparation of chelating resin with formaldehyde, which finds application in separation and concentration of silver ions.
Solubility
Soluble in acetone and chloroform. Insoluble in water.
Notes
Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- Firouzabadi, H.; Iranpoor, N.; Gorginpour, F.; Samadi, A. Dithiooxamide as an Effective Sulfur Surrogate for Odorless High-Yielding Carbon-Sulfur Bond Formation in Wet PEG200 as an Eco-Friendly, Safe, and Recoverable Solvent. Eur. J. Org. Chem. 2015, 2015 (13), 2914-2920.
- Mikhailov, O. V.; Chachkov, D. V. Possibility of template synthesis with junction of metallacycles containingtrans-located nitrogen atoms in the 3d metal(II) ion-dithiooxamide-acetone systems as predicted by DFT simulation data. Russ. J. Gen. Chem. 2015, 85 (3), 628-633.