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Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals

Thermo Scientific Chemicals

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals

Name: Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals
SKU: H25883.03
Price: 122.65 USD

CAS: 142421-57-6 | C16H6ClF12P | 492.629 g/mol

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Catalog number H25883.03

also known as H25883-03

Price (USD)

122.65

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Quantity:

1 g

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Price (USD)

122.65

Online Exclusive

136.00

Save 13.35 (10%)

Each

Chemical Identifiers

CAS142421-57-6

IUPAC Namebis[3,5-bis(trifluoromethyl)phenyl](chloro)phosphane

Molecular FormulaC16H6ClF12P

InChI KeyDFZQEHBNAJGDCT-UHFFFAOYSA-N

SMILESFC(F)(F)C1=CC(=CC(=C1)P(Cl)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F

Specifications

Specification Sheet

Appearance (Color)White/colorless to pale yellow

FormFused or crystalline low melting solid

Assay by NMR≥96.0.% (31-P NMR)

CommentMelt may contain suspended crystals of amine hydrochloride from manufacturing process

Proton NMRConforms to structure

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

RUO – Research Use Only

General References:

Hong Jin; Da-yu Wang; Yi-fang Mei; Wen-bing Qiu; Yi Zhou; Dong-ming Wang; Xue-rui Tan; Yu-guang Li. Mitogen-activated protein kinases pathway is involved in physiological testosterone-induced tissue factor pathway inhibitor expression in endothelial cells. Blood Coagulation and Fibrinolysis. 2010, 21 (5), 420-424.
R. Oost; J. Rong; A. J. Minnaard and S. R. Harutyunyan. Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis. Catal. Sci. Technol. 2014, 4 (7), 1997-2005.