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1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals
1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals
1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals

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Catalog number H27057.03
also known as H27057-03
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Quantity:
1 g
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Chemical Identifiers
CAS97239-80-0
IUPAC Name1,1'-Bis(diisopropylphosphino)ferrocene
Molecular FormulaC22H36FeP2
SMILES[Fe].CC(C)P(C(C)C)c1cccc1.CC(C)P(C(C)C)c1cccc1
Molecular Weight (g/mol)418.32
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SpecificationsSpecification SheetSpecification Sheet
FormPowder
Chloride content(by ICP): <200ppm : UK sourced material ONLY
Proton NMRConforms to structure (Assay: >97.0%)
Phosphorus-31 NMRConforms to structure (Assay: >99.0%)
Appearance (Color)Yellow to orange
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Snegur,; L.V.; Simenel,; A. A.; Rodionov,; A. N.; Boev, V. I. Ferrocene modification of organic compounds for medicinal applications. Russ. Chem. Bull. 2014 , 63 26-36.
  2. Joyce H. L. Ong,; Chip Nataro,; James A. Golen,; Arnold L. Rheingold. Electrochemistry of Late Transition Metal Complexes Containing the Ligand 1,1‘-Bis(diisopropylphosphino)ferrocene (dippf) . Organometallics. 2003, 22(24), 5027-5032.