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Titanium(IV) chloride, 1M soln. in dichloromethane
Titanium(IV) chloride, 1M soln. in dichloromethane
Titanium(IV) chloride, 1M soln. in dichloromethane
Thermo Scientific Chemicals

Titanium(IV) chloride, 1M soln. in dichloromethane

CAS: 7550-45-0 | Cl4Ti | 189.667 g/mol
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Catalog number H31830.AE
also known as H31830-AE
Price (USD)
65.80
Each
Quantity:
100 mL
Request bulk or custom format
Price (USD)
65.80
Each
Chemical Identifiers
CAS7550-45-0
IUPAC Nametitanium(4+) tetrachloride
Molecular FormulaCl4Ti
InChI KeyXJDNKRIXUMDJCW-UHFFFAOYSA-J
SMILES[Cl-].[Cl-].[Cl-].[Cl-].[Ti+4]
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Colorless to pale yellow to dark brown
FormLiquid
Assay (Titration ex Chloride)0.95-1.10M
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines

Solubility
Reacts with water.

Notes
Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers
WARNING: Cancer – www.P65Warnings.ca.gov
RUO – Research Use Only

General References:

  1. Min Shi.; Jian-Kang Jiang.; Yan-Shu Feng. Titanium(IV) Chloride and the Amine-Promoted Baylis-Hillman Reaction. Org. Lett. 2000, 16, (2), 2397-2400.
  2. Min Shi.; Yan-Shu Feng. Titanium(IV) Chloride and Quaternary Ammonium Salt Promoted Baylis-Hillman Reaction. J. Org. Chem. 2001, 66, (2), 406-411.