Search
Element Search
Structure Search
Thermo Scientific Chemicals
(Bromomethyl)cyclopropane, 97%
CAS: 7051-34-5 | C4H7Br | 135.00 g/mol
Have Questions?
Change view
Catalog number L01122.03
also known as L01122-03
Price (USD)
43.65
Online Exclusive
48.70Save 5.05 (10%)
Each
Quantity:
1 g
Price (USD)
43.65
Online Exclusive
48.70Save 5.05 (10%)
Each
Chemical Identifiers
CAS7051-34-5
IUPAC Name(bromomethyl)cyclopropane
Molecular FormulaC4H7Br
InChI KeyAEILLAXRDHDKDY-UHFFFAOYSA-N
SMILESBrCC1CC1
View more
Specifications
Specification Sheet
Specification SheetFormliquid
Appearance (Color)Clear, colourless to pale yellow
Assay (GC)≥ 96.0%
Identification (FTIR)Conforms
Refractive Index1.4745 - 1.4795 @20?C
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents. It has been used as a synthetic building block for the introduction of the cyclopropylmethyl group.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents. It has been used as a synthetic building block for the introduction of the cyclopropylmethyl group.
Solubility
Not miscible in water.
Notes
Protect from heat. Store away from oxidizing agents. Incompatible with strong bases, strong oxidizing agents.
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents. It has been used as a synthetic building block for the introduction of the cyclopropylmethyl group.
Solubility
Not miscible in water.
Notes
Protect from heat. Store away from oxidizing agents. Incompatible with strong bases, strong oxidizing agents.
RUO – Research Use Only
General References:
- M.A. Mohammadi, W.V.F. Brooks. The microwave spectrum and conformation of bromomethyl cyclopropane.Journal of Molecular Spectroscopy.1979, 77 42-47 .
- O-Alkylation of phenols (KO-t-Bu/DMF) has been used as a means of protection. The cyclopropylmethyl ethers are stable to reducing agents (metal hydride, H2, Birch), but selectively cleaved by aqueous methanolic HCl: Chem. Pharm. Bull., 23, 2878 (1975).