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Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%
Thermo Scientific Chemicals

Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%

CAS: 175136-62-6 | C24H9F18P | 670.281 g/mol
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Quantity:
250 mg
1 g
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Catalog number L06941.03
also known as L06941-03
Price (USD)
149.00
Each
Quantity:
1 g
Request bulk or custom format
Price (USD)
149.00
Each
Chemical Identifiers
CAS175136-62-6
IUPAC Nametris[3,5-bis(trifluoromethyl)phenyl]phosphane
Molecular FormulaC24H9F18P
InChI KeyITJHLZVYLDBFOJ-UHFFFAOYSA-N
SMILESFC(F)(F)C1=CC(=CC(=C1)P(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F
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SpecificationsSpecification SheetSpecification Sheet
Identification (FTIR)Conforms
FormCrystals or powder or crystalline powder
Melting Point (clear melt)94.0-107.0?C
Appearance (Color)Pale cream to cream to yellow to brown
Assay (GC)≥92.0%
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine is used as ligands which is useful as catalysts in various reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tris[3,5-bis(trifluoromethyl)phenyl]phosphine is used as ligands which is useful as catalysts in various reactions.

Solubility
Insoluble in water.

Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.
RUO – Research Use Only

General References:

  1. Shin-ichiro Fujita; Shinya Fujisawa; Bhalchandra M.Bhanage; Masahiko Arai. Rhodium-tris(3,5-bis(trifluoromethyl)phenyl)phosphine catalyzed hydroformylation of dienes to dialdehydes in supercritical carbon dioxide with high activity. Tetrahedron Letters. 2004, 45,(6), 1307-1310.
  2. Tatsuo Ishiyama; Hironori Isou; Takao Kikuchi; Norio Miyaura. Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes. Chem. Commun. 2010, 46,(1), 159-161.
  3. In a study of coupling reactions in supercritical CO2, catalyzed by Tris(dibenzyl ideneacetone) dipalladium(0) , 12760, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tri(2-furyl) phosphine, L13329, Tris(pentafluorophenyl) phosphine, L02748