Propiolaldehyde diethyl acetal, 97%
Propiolaldehyde diethyl acetal, 97%
Propiolaldehyde diethyl acetal, 97%
Thermo Scientific Chemicals

Propiolaldehyde diethyl acetal, 97%

CAS: 10160-87-9 | C7H12O2 | 128.17 g/mol
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25 g
Catalog number L10767.14
also known as L10767-14
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440.65
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489.00
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Quantity:
25 g
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Price (USD)
440.65
Online Exclusive
489.00
Save 48.35 (10%)
Each
Chemical Identifiers
CAS10160-87-9
IUPAC Name3,3-diethoxyprop-1-yne
Molecular FormulaC7H12O2
InChI KeyRGUXEWWHSQGVRZ-UHFFFAOYSA-N
SMILESCCOC(OCC)C#C
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SpecificationsSpecification SheetSpecification Sheet
FormLiquid
Assay (GC)≥96.0%
Appearance (Color)Clear colorless to yellow
CommentMaterial sourced in the U.S. and in other countries
Refractive Index1.4100-1.4150 @ 20°C (non-U.S. sourced material)
Propiolaldehyde diethyl acetal is used in preparation of 3-boronoacrolein pinacolate, a heterodyne and (E)-3-(tributylstannyl)-2-propenal.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Propiolaldehyde diethyl acetal is used in preparation of 3-boronoacrolein pinacolate, a heterodyne and (E)-3-(tributylstannyl)-2-propenal.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Air and moisture sensitive. Store under inert gas.
RUO – Research Use Only

General References:

  1. Xuri Gao.; Dennis G Hall. 3-Boronoacrolein as an exceptional heterodiene in the highly enantio- and diastereoselective Cr(III)-catalyzed three-component [4+2]/allylboration.. Journal of the American Chemical Society. 2003, 125 (31), 9308-9309.
  2. Roswitha Ostwald.; Pierre-Yves Chavant.; Heinz Stadtmueller.; Paul Knochel. Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to .beta.-Stannylated and .beta.-Silylated Unsaturated Aldehydes. J. Org. Chem. 1994, 59 (15), 4143-4153.