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Thermo Scientific Chemicals
4'-Chloro-2,2':6',2″-terpyridine, 98%
CAS: 128143-89-5 | C15H10ClN3 | 267.72 g/mol
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Chemical Identifiers
CAS128143-89-5
IUPAC Name4-chloro-6-(pyridin-2-yl)-2,2'-bipyridine
Molecular FormulaC15H10ClN3
InChI KeyAHEMFMCEBIJRMU-UHFFFAOYSA-N
SMILESClC1=CC(=NC(=C1)C1=CC=CC=N1)C1=CC=CC=N1
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Specifications
Specification Sheet
Specification SheetMelting Point (clear melt)148.0-155.0?C
FormCrystals or powder or crystalline powder
Identification (FTIR)Conforms
Appearance (Color)White to cream
Assay (GC)≥97.5%
4'-Chloro-2,2':6',2″-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4′-Chloro-2,2′:6′,2′′-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).
Solubility
Slightly soluble in water.
Notes
Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
4′-Chloro-2,2′:6′,2′′-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,µ-bishydroxy-functionalized poly(propylene oxide).
Solubility
Slightly soluble in water.
Notes
Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
RUO – Research Use Only
General References:
- Zhang, G.; Tan, J.; Zhang, Y. Z.; Ta, C.; Sanchez, S.; Cheng, S. Y.; Golen, J. A.; Rheingold, A. L. Syntheses, structures and cytotoxicity of cobalt(II) complexes with 4'-chloro-2,2':6',2″-terpyridine. Inorg. Chim. Acta 2015, 435, 147-152.
- Saghatforoush, L. A.; Valencia, L.; Chalabian, F.; Ghammamy, S.; Khaledi, L. Z. Synthesis, crystal structure, and biological activity of 4'-chloro-2,2' : 6',2″-terpyridine (Cltpy) as tridentate ligand in a Cd(II) complex. J. Coord. Chem. 2011, 64 (19), 3311-3322.