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2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 94%
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 94%
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 94%
Thermo Scientific Chemicals

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 94%

CAS: 61676-62-8 | C9H19BO3 | 186.058 g/mol
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25 g
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Catalog number L17278.14
also known as L17278-14
Price (USD)
93.65
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104.00
Save 10.35 (10%)
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Quantity:
25 g
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Price (USD)
93.65
Online Exclusive
104.00
Save 10.35 (10%)
Each
Chemical Identifiers
CAS61676-62-8
IUPAC Name4,4,5,5-tetramethyl-2-(propan-2-yloxy)-1,3,2-dioxaborolane
Molecular FormulaC9H19BO3
InChI KeyMRWWWZLJWNIEEJ-UHFFFAOYSA-N
SMILESCC(C)OB1OC(C)(C)C(C)(C)O1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear colorless
Assay (GC)≥92.0%
Identification (FTIR)Conforms
FormLiquid
Refractive Index1.4070-1.4110 @ 20?C
Reagent for fluorenylborolane preparation, reagent used to borylate arenes. Reagent used to borylate arenes and for fluorenylborolane preparation.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reagent for fluorenylborolane preparation, reagent used to borylate arenes. Reagent used to borylate arenes and for fluorenylborolane preparation.

Solubility
Soluble in water.

Notes
Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
RUO – Research Use Only

General References:

  1. Laurent Deloux.; Morris Srebnik. Preparation of (Z)-1-Alkenyl Dioxaborolanes by Hydrolysis of Boryl Zirconocene 1,1-Dimetalloalkenes. J. Org. Chem. 1994, 59 (22), 6871-6873.
  2. Maxime Ranger.; Dany Rondeau.; Mario Leclerc. New Well-Defined Poly(2,7-fluorene) Derivatives: Photoluminescence and Base Doping. Macromolecules. 1997, 30 (25), 7686-7691.
  3. Selective reagent for preparation of pinacol boronic esters, e.g. for preparation of allenyl or vinyl pinacol boronates from the Grignard or lithium reagents: Liebigs Ann. Chem., 881 (1987); Chem. Ber., 122, 1777 (1989); Tetrahedron Lett., 33, 6941 (1992).